Method for forming cooperative binary ionic solids
| DWPI Title: Forming nanostructured molecular unit, comprises mixing cationic porphyrin in first solvent, anionic porphyrin in second solvent, and forming by self-assembly nanostructured molecular unit with morphology comprising four dendritic elements |
| Abstract: A nanostructured molecular unit and method for forming is described where a cationic porphyrin having an ethanolic substituent species and a metal in the porphyrin cavity is combined with an anionic porphyrin having a sulfonate substituent species and a metal in the porphyrin cavity to form by self-assembly a nanostructured molecular unit with a morphology comprising four dendritic elements connected at a central node. |
| Use: The method is useful for forming a nanostructured molecular unit. |
| Novelty: Forming a nanostructured molecular unit comprises mixing at least one cationic porphyrin in a first solvent, where the cationic porphyrin comprises ethanolic substituent species, and at least one anionic porphyrin in a second solvent, the anionic porphyrin comprises sulfonate substituent species, and forming by self-assembly a nanostructured molecular unit with a morphology comprising four dendritic elements connected at a central node. |
| Filed: 2/4/2013 |
| Application Number: US13758469A |
| Tech ID: SD 11429.1 |
| This invention was made with Government support under Contract No. DE-NA0003525 awarded by the United States Department of Energy/National Nuclear Security Administration. The Government has certain rights in the invention. |
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